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حذف نیترات از پساب شهری در فرآیند جذب سطحی بر روی کربن فعال پوست پرتقال اصلاح شده با کیتوسان و ذرات آهن | ||
| نشریه مهندسی عمران امیرکبیر | ||
| مقاله 3، دوره 54، شماره 7، مهر 1401، صفحه 2493-2508 اصل مقاله (1.78 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22060/ceej.2021.19667.7228 | ||
| نویسندگان | ||
| خدیجه امیرسادات؛ حکیمه شریفی فرد* ؛ اصغر لشنی زادگان | ||
| دانشکده فنی و مهندسی، دانشگاه یاسوج، یاسوج، ایران | ||
| چکیده | ||
| حذف نیترات از آبهای آلوده یکی از مباحث مهم زیست محیطی است. هدف از این مطالعه، حذف نیترات از پساب شهری توسط کربن فعال پوست پرتقال اصلاح شده با کیتوسان سنتز شده از پوست میگو و آهن (ш) کلراید میباشد. شناسایی گروههای عاملی کربن فعال به وسیلهی FTIR، مورفولوژی حفرات کربن سنتز شده توسطSEM و خواص تخلخلی با آنالیز BET بررسی شد. نتایج شناسایی بیانگر ساختار متخلخل و با گروههای عاملی مختلف کربن فعال اصلاح شده است. از مدلهای سینتیکی شبه مرتبه اول، شبه مرتبه دوم، نفوذ درون ذرهای و بوید به منظور توصیف دادههای سینتیکی و همچنین ایزوترمهای لانگمویر، فروندلیچ و دوبینین- رادوشکوویچ برای توصیف دادههای تعادلی جذب استفاده گردید. اثر پارامترهای pH و مقدار جاذب بررسی شد و نتایج نشان داد که pH=2 و مقدار جاذب 0/2 گرم در 50 میلیلیتر محلول شرایط بهینه برای رسیدن به حداکثر حذف نیترات میباشند. نتایج نشان داد که جذب از سینتیک شبه مرتبه دوم پیروی میکند (1=R2). همچنین در بین ایزوترمهای مورد بررسی، مدل لانگمویر جذب نیترات بر روی کربن فعال سنتز شده را به خوبی توصیف نمود (0/9999=R2) و حداکثر ظرفیت جذب 263/157 میلیگرم بر گرم کربن فعال بود. این رفتار به معنی جذب تک لایه و غالب بودن مکانیسم جذب شیمیایی است. مقدار جذب نیترات با کاهش دما افزایش یافت که نشان دهندهی گرمازا بودن واکنش میباشد. راندمان حذف نیترات با کربن فعال اصلاح شده 99/58% برآورد شد. به طور کلی میتوان گفت کربن فعال اصلاح شده میتواند کاندیدی برای استفاده در مقیاس صنعتی باشد. | ||
| کلیدواژهها | ||
| نیترات؛ جذب سطحی؛ کربن فعال؛ پساب شهری؛ راندمان حذف | ||
| موضوعات | ||
| آلودگی آب ، فاضلاب؛ مهندسی محیط زیست | ||
| عنوان مقاله [English] | ||
| Nitrate removal from municipal effluent in the adsorption process on activated carbon of orange peel modified with chitosan and iron particles | ||
| نویسندگان [English] | ||
| Khadijeh Amirsadat؛ hakimeh sharififard؛ asghar lashanizadegan | ||
| Chemical engineering department, yasouj university, yasouj | ||
| چکیده [English] | ||
| Nitrate removal from polluted waters is one of the most important environmental issues. The aim of this study was to remove nitrate from municipal effluent by activated carbon of orange peel modified with chitosan synthesized from shrimp peel and iron (ш) chloride. Identification of activated carbon functional groups by FTIR, the morphology of carbon cavities by SEM, and porosity properties were investigated by BET analysis. The characterization results indicate a porous structure with different functional groups of modified activated carbon. Pseudo-first-order, pseudo-second-order, intra-particle, and Boyd kinetic models were used to describe the kinetic data, as well as Langmuir, Freundlich, and Dubinin-Radushkevitch isotherms to describe the adsorption equilibrium data. The effect of pH and the amount of adsorbent was investigated and the results showed that pH = 2 and the amount of adsorbent 0.2 g in 50 ml of solution are the optimal conditions to achieve maximum nitrate removal. The results showed that the adsorption followed the pseudo-second-order kinetics (R2 = 1). Also, among the studied isotherms, the Langmuir model described well the adsorption of nitrate onto synthesized activated carbon (R2 = 0.999) and the maximum adsorption capacity was 263.157 mg/g of activated carbon. This behavior means the adsorption of the monolayer and the predominance of the chemical adsorption mechanism. Nitrate uptake increased with decreasing temperature, indicating that the reaction was exothermic. Nitrate removal efficiency with modified activated carbon was estimated to be 99.58%. In general, it can be said that modified carbon can be a candidate for use on an industrial scale. | ||
| کلیدواژهها [English] | ||
| Nitrate, Adsorption, Activated carbon, Urban Wastewater, Removal efficiency | ||
| مراجع | ||
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[1] N. Mehrabi, M. Soleimani, M.M. Yeganeh, H. Sharififard, Parameter optimization for nitrate removal from water using activated carbon and composite of activated carbon and Fe2O3 nanoparticles, RSC advances, 5(64) (2015) 51470-51482. [2] P.C. Mishra, R.K. Patel, Use of agricultural waste for the removal of nitrate-nitrogen from aqueous medium, Journal of Eenvironmental Management, 90(1) (2009) 519-522. [3] J.M. Rodríguez-Maroto, F. García-Herruzo, A. García-Rubio, C. Gómez-Lahoz, C. Vereda-Alonso, Kinetics of the chemical reduction of nitrate by zero-valent iron, Chemosphere, 74(6) (2009) 804-809. [4] T.M. Addiscott, A.P. Whitmore, D.S. Powlson, Farming, fertilizers and the nitrate problem, CAB International (CABI), 1991. [5] S. Water, O. World Health, Guidelines for drinking-water quality [electronic resource]: incorporating first addendum. Vol. 1, Recommendations, (2006). [6] L.C. Neri, H.L. Johansen, D. Hewitt, J. Marier, N. Langner, Magnesium and certain other elements and cardiovascular disease, Science of the Total Environment, 42(1-2) (1985) 49-75. [7] H. Sharififard, A. Lashnizadegan, Z. Hashemi-shahraki, Modeling the mass transfer of the adsorption process of cadmium with activated carbon synthesized from grape pulp, Iranian Journal of Chemistry and Chemical Engineering, (2017), (in persian). [8] S. Chatterjee, D.S. Lee, M.W. Lee, S.H. Woo, Nitrate removal from aqueous solutions by cross-linked chitosan beads conditioned with sodium bisulfate, Journal of Hazardous Materials, 166(1) (2009) 508-513. [9] M. Ahmadi, H. Rahmani, B. Ramavandi, B. Kakavandi, Removal of nitrate from aqueous solution using activated carbon modified with Fenton reagents, Desalination and Water Treatment, 76 (2017) 265-275. [10] R.S. Dongre, Phosphate & nitrate removal from agricultural runoff by chitosan-graphite composite, Research & Development in Material Science, (2018) 11. [11] A. Alighardashi, Z. Kashitarash Esfahani, F. Najafi, Investigating the efficiency of functionalized PAMAM-GO nano-composite for nitrate removal from aqua solutions, Journal of Water and Wastewater; Ab va Fazilab (in persian), 29(6) (2019) 79-90. [12] M. Farasati, S. Boroomand Nasab, H. Moazed, N. Jafarzadeh Haghighifard, J. Abedi Koupai, M. Seyedian, Nitrate removal from contaminated waters by using anion exchanger phragmites australis nanoparticles, Journal of Water and Wastewater; Ab va Fazilab (in persian), 24(1) (2013) 34-42. [13] A. Pourkhabbaz, A. Zeidi, F. Mehrjo, Survey of nitrate removal method from aqueous solutions using titanium dioxide nano-photocatalyst, Journal of Health, 10(4) (2020) 396-410. [14] H. Golstanifar, S. Nasseri, A.H. Mahvi, M.H. Dehghani, A. Asadi, Evaluation of aluminum powder efficiency in removal of nitrate from aqueous solutions, Journal of Health and Hygiene, 2(5) (2011) 36-40. [15] M.T. Ghaneian, M.H. Ehrampoush, M. Safdari, M. Emamjomeh, M. Askarishahi, Performance of olive pit ash's in nitrate removal from the aqueous solutions, Tolooebehdasht, 13(2) (2014) 168-177. [16] H. Demiral, G. Gündüzoğlu, Removal of nitrate from aqueous solutions by activated carbon prepared from sugar beet bagasse, Bioresource Technology, 101(6) (2010) 1675-1680. [17] L. Niazi, A. Lashanizadegan, H. Sharififard, Chestnut oak shells activated carbon: Preparation, characterization and application for Cr (VI) removal from dilute aqueous solutions, Journal of Cleaner Production, 185 (2018) 554-561. [18] Z.H. shahraki, H. Sharififard, A. Lashanizadegan, Grape stalks biomass as raw material for activated carbon production: synthesis, characterization and adsorption ability, Materials Research Express, 5(5) (2018) 055603. [19] H. Sharififard, E. Rezvanpanah, S.H. Rad, A novel natural chitosan/activated carbon/iron bio-nanocomposite: Sonochemical synthesis, characterization, and application for cadmium removal in batch and continuous adsorption process, Bioresource Technology, 270 (2018) 562-569. [20] Ş. Taşar, F. Kaya, A. Özer, Biosorption of lead (II) ions from aqueous solution by peanut shells: equilibrium, thermodynamic and kinetic studies, Journal of Environmental Chemical Engineering, 2(2) (2014) 1018-1026. [21] G. Vázquez, M.S. Freire, J. González-Alvarez, G. Antorrena, Equilibrium and kinetic modelling of the adsorption of Cd2+ ions onto chestnut shell, Desalination, 249(2) (2009) 855-860. [22] Z. Hu, L. Lei, Y. Li, Y. Ni, Chromium adsorption on high-performance activated carbons from aqueous solution, Separation and Purification Technology, 31(1) (2003) 13-18. [23] M. Barkat, D. Nibou, S. Chegrouche, A. Mellah, Kinetics and thermodynamics studies of chromium (VI) ions adsorption onto activated carbon from aqueous solutions, Chemical Engineering and Processing: Process Intensification, 48(1) (2009) 38-47. [24] R.M. Ali, H.A. Hamad, M.M. Hussein, G.F. Malash, Potential of using green adsorbent of heavy metal removal from aqueous solutions: adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis, Ecological Engineering, 91 (2016) 317-332. [25] F. Deniz, Potential use of shell biomass (Juglans regia L.) for dye removal: Relationships between kinetic pseudo-second-order model parameters and biosorption efficiency, Desalination and Water Treatment, 52(1-3) (2014) 219-226. [26] M. Naushad, M.A. Khan, Z.A. Alothman, M.R. Khan, M. Kumar, Adsorption of methylene blue on chemically modified pine nut shells in single and binary systems: isotherms, kinetics, and thermodynamic studies. Desalination and Water Treatment, 57 (2015) 15848–15861. [27] H. Sharififard, F. Pepe, M. Soleimani, P. Aprea, D. Caputo, Iron-activated carbon nanocomposite: synthesis, characterization and application for lead removal from aqueous solution, RSC Advances, 6(49) (2016) 42845-42853. [28] G.E. Boyd, A.W. Adamson, L.S. Myers Jr, The exchange adsorption of ions from aqueous solutions by organic zeolites. II. Kinetics1, Journal of the American Chemical Society, 69(11) (1947) 2836-2848. [29] G. Limousin, J.P. Gaudet, L. Charlet, S. Szenknect, V. Barthes, M. Krimissa, Sorption isotherms: A review on physical bases, modeling and measurement, Applied Geochemistry, 22(2) (2007) 249-275. [30] D. Mohan, C.U. Pittman Jr, Activated carbons and low cost adsorbents for remediation of tri-and hexavalent chromium from water, Journal of Hazardous Materials, 137(2) (2006) 762-811. [31] M.H. Beyki, H. Alijani, Y. Fazli, Poly o-phenylenediamine–MgAl@ CaFe2O4 nanohybrid for effective removing of lead (II), chromium (III) and anionic azo dye, Process Safety and Environmental Protection, 102 (2016) 687-699. [32] S. Asgarzadeh, R. Rostamian, E. Faez, A. Maleki, H. Daraei, Biosorption of Pb (II), Cu (II), and Ni (II) ions onto novel lowcost P. eldarica leaves-based biosorbent: isotherm, kinetics, and operational parameters investigation, Desalination and Water Treatment, 57(31) (2016) 14544-14551. [33] J. Febrianto, A.N. Kosasih, J. Sunarso, Y.-H. Ju, N. Indraswati, S. Ismadji, Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: a summary of recent studies, Journal of Hazardous Materials, 162(2-3) (2009) 616-645. [34] Y. Sağ, Y. Aktay, Kinetic studies on sorption of Cr (VI) and Cu (II) ions by chitin, chitosan and Rhizopus arrhizus, Biochemical Engineering Journal, 12(2) (2002) 143-153. [35] C. Namasivayam, D. Sangeetha, Removal and recovery of vanadium (V) by adsorption onto ZnCl2 activated carbon: kinetics and isotherms, Adsorption, 12(2) (2006) 103-117. [36] Z. Elouear, J. Bouzid, N. Boujelben, M. Feki, F. Jamoussi, A. Montiel, Heavy metal removal from aqueous solutions by activated phosphate rock, Journal of Hazardous Materials, 156(1-3) (2008) 412-420. [37] C. Namasivayam, M.V. Sureshkumar, Removal and recovery of molybdenum from aqueous solutions by adsorption onto surfactant‐modified coir pith, a lignocellulosic polymer, CLEAN–Soil, Air, Water, 37(1) (2009) 60-66. [38] T. Mathialagan, T. Viraraghavan, Biosorption of pentachlorophenol from aqueous solutions by a fungal biomass, Bioresource Technology, 100(2) (2009) 549-558. [39] P.N. Fotsing, N. Bouazizi, E.D. Woumfo, N. Mofaddel, F. Le Derf, J. Vieillard, Investigation of chromate and nitrate removal by adsorption at the surface of an amine-modified cocoa shell adsorbent, Journal of Environmental Chemical Engineering, 9(1) (2021) 104618. [40] P. Karthikeyan, S.S. Elanchezhiyan, J. Preethi, K. Talukdar, S. Meenakshi, C.M. Park, Two-dimensional (2D) Ti3C2Tx MXene nanosheets with superior adsorption behavior for phosphate and nitrate ions from the aqueous environment, Ceramics International, 47(1) (2021) 732-739. [41] P. Karthikeyan, S. Meenakshi, Fabrication of hybrid chitosan encapsulated magnetic-kaolin beads for adsorption of phosphate and nitrate ions from aqueous solutions, International Journal of Biological Macromolecules, 168 (2021) 750-759. [42] S. Rahdar, K. Pal, L. Mohammadi, A. Rahdar, Y. Goharniya, S. Samani, G.Z. Kyzas, Response surface methodology for the removal of nitrate ions by adsorption onto copper oxide nanoparticles, Journal of Molecular Structure, 1231 (2021) 129686. [43] Y. Wang, X. Song, Z. Xu, X. Cao, J. Song, W. Huang, X. Ge, H. Wang, Adsorption of nitrate and ammonium from water simultaneously using composite adsorbents constructed with functionalized biochar and modified zeolite, Water, Air, & Soil Pollution, 232(5) (2021) 1-19. [44] H. Nassar, A. Zyoud, A. El-Hamouz, R. Tanbour, N. Halayqa, H.S. Hilal, Aqueous nitrate ion adsorption/desorption by olive solid waste-based carbon activated using ZnCl2, Sustainable Chemistry and Pharmacy, 18 (2020) 100335. [45] Q. Hu, H. Liu, Z. Zhang, Y. Xie, Nitrate removal from aqueous solution using polyaniline modified activated carbon: Optimization and characterization, Journal of Molecular Liquids, 309 (2020) 113057. | ||
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